Vinceres is a demonic assassin, a timeless, unstoppable hit man who keeps going until he gets his target. He is immune to witchs power. 
Vince possesses the power to burn people with the touch of his hand. An empath cursed Vince by passing on his gift to him to make him feel the pain that he inflicts. However he could trick Prue to remove them so that she unknowingly received them instead.

Vince was vanquished by Prue's astral projection with the human emotions she could read.

Empaths are mortals who can actually feel what other people feel. It's a rare gift. 
Empaths often blend into society as councilors, elders, teachers. 
They use their sensitivity to guide mortals, ease their pain, even heal them.

to remove the empathic skills:

Free the empath release his gift, 
let his pain be cast adrift

Prue casts a misguided spell that releases Vince a demon from his curse, while at the same time turning her into an empath, able to feel all the pain in the world. Meanwhile, Piper and Leo try to put a little normalcy into their relationship, while Phoebe tries to understand why Cole is pulling away from her.

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